Angewandte Chemie · 2016 · 57 citations · 50 references
Materials ScienceCatalytic ApplicationUnique PorosityEngineeringNanoporous MaterialNanomaterialsNanotechnologyMesoporous Silicalite‐1 NanocrystalsCatalyst RecyclingAbstract Pd NanoparticlesNanoheterogeneous CatalysisCatalysisChemistryCatalyst PreparationZeoliteFunctional MaterialsShape‐selective Catalysis
Abstract Pd nanoparticles were successfully encapsulated inside mesoporous silicalite‐1 nanocrystals (Pd@mnc‐S1) by a one‐pot method. The as‐synthesized Pd@mnc‐S1 with excellent stability functioned as an active and reusable heterogeneous catalyst. The unique porosity and nanostructure of silicalite‐1 crystals endowed the Pd@mnc‐S1 material general shape‐selectivity for various catalytic reactions, including selective hydrogenation, oxidation, and carbon–carbon coupling reactions.
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