Publication | Closed Access
A <i>C</i><sub>3</sub>‐Symmetric Macrocycle‐Based, Hydrogen‐Bonded, Multiporous Hexagonal Network as a Motif of Porous Molecular Crystals
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Citations
41
References
2015
Year
Materials ScienceSupramolecular AssemblyEngineeringMacromolecular EngineeringMultiporous Hexagonal NetworkCovalent Bonded FrameworkCo 2Molecule-based MaterialMolecular TectonicsOrganic ChemistryPorous Molecular CrystalsChemistrySupramolecular ChemistryCavity VolumeHybrid MaterialsCrystallographyMetal-organic FrameworksCrystalline Supramolecular Frameworks
Abstract A C 3 ‐symmetric π‐conjugated macrocycle combined with an appropriate hydrogen bonding module (phenylene triangle) allowed the construction of crystalline supramolecular frameworks with a cavity volume of up to 58 %. The frameworks were obtained through non‐interpenetrated stacking of a hexagonal sheet possessing three kinds of pores with different sizes and shapes. The activated porous material absorbed CO 2 up to 96 cm 3 g −1 at 195 K under 1 atm.
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