An Isolable Mixed P,S‐Bis(ylide) as an Asymmetric Carbon Atom Source

Abstract

Herz aus Kohlenstoff: Das erste stabile asymmetrische Bis(ylid) – N,N′-(iPr2NCH2CH2NiPr)(Ph)PCSPh2 –wurde isoliert (siehe Bild; C schwarz, N grau). Die Gegenwart der beiden unterschiedlichen Liganden bewirkt, dass dieser Kohlenstoff(0)-Komplex als asymmetrische Quelle für atomaren Kohlenstoff fungiert. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.