A Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading

Abstract

Ein luftbeständiger Palladiumkatalysator mit dreizähnigem Phosphanligand aryliert elektronenreiche wie elektronenarme mehrfach substituierte Furane (X=O), Thiophene (X=S) und Pyrrole (X=NR5) sowie Thiazole direkt unter C-H-Aktivierung mit Chlorarenen (siehe Schema; DMAc=N,N-Dimethylacetamid, TBAB=Tetra-n-butylammoniumbromid). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.