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Enantioselective Formation of All‐Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group
80
Citations
63
References
2014
Year
Chemical EngineeringEngineeringNatural SciencesCompetitive EliminationDiversity-oriented SynthesisAll‐carbon Quaternary StereocentersAbstract DescribedOrganic ChemistryCatalysisStereoselective SynthesisChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisEnantioselective FormationUseful Indole Products
Abstract Described is an efficient catalytic asymmetric intermolecular CC bond‐formation process to generate acyclic all‐carbon quaternary stereocenters. The reactions overcome the unfavorable steric hindrance around reactive centers, and the competitive elimination (E1), to form a range of useful indole products with excellent efficiency and enantioselectivity.
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