Isomerization Polymerization of the Phosphaalkene MesPCPh₂: An Alternative Microstructure for Poly(methylenephosphine)s

Abstract

Einzigartige Route: Die radikalische Additionspolymerisation von MesPCPh2 verläuft über die C-H-Aktivierung einer ortho-CH3-Gruppe des Mes-Restes (siehe Schema; Mes=2,4,6-Trimethylphenyl, tht=Tetrahydrothiophen, TEMPO=2,2,6,6-Tetramethyl-l-piperidinoxyl). Dieser einzigartige Mechanismus der Isomerisierungspolymerisation steht im Kontrast zur früher vorgeschlagenen, für Olefine typischen Kopf-Schwanz-Verkettung. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.