Total Syntheses of Heimiol A, Hopeahainol D, and Constrained Analogues

Abstract

Ein Reagens namens IDSI, [(Et2SI)2Cl⋅ SbCl6], löst eine sorgsam entworfene Reaktionskaskade aus, die den zentralen [3.2.2]Bicyclus beider Zielverbindungen, 1 und 2, in einer einzigen stereokontrollierten Operation liefert. Auf dem weiteren Weg zu den Naturstoffen wurden Spannungsenergien genutzt. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.