Symmetry Breaking in the Self‐Assembly of Partially Fluorinated Benzene‐1,3,5‐tricarboxamides

Abstract

Das Zusammenspiel von zwei aufeinanderfolgenden Aggregationsprozessen führt zum Symmetriebruch in einem achiralen selbstorganisierenden System. Fluorierte Benzol-1,3,5-tricarboxamid-Moleküle bilden zunächst eine racemische Mischung aus P- und M-helikalen Aggregaten, die sich zu optisch aktiven Aggregaten höherer Ordnung oder Fasern bündeln (siehe Bild). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.