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Dirhodium(II) Carboxylate Catalyzed Formation of 1,2,3‐Trisubstituted Indoles from Styryl Azides
20
Citations
49
References
2013
Year
Chemical EngineeringEngineeringStyryl AzidesCoordination ComplexOrganic ChemistrySelective MigrationCatalysisOrganometallic CatalysisChemistrySynthesis MethodAbstract DirhodiumMolecular ComplexSynthetic ChemistryAcyl GroupsBiomolecular Engineering
Abstract Dirhodium(II)‐carboxylate complexes were discovered to promote the selective migration of acyl groups in trisubstituted styryl azides to form 1,2,3‐trisubstituted indoles. The styryl azides are readily available in three steps from cyclobutanone and 2‐iodoaniline.
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