Monthly Notices of the Royal Astronomical Society · 1982 · 219 citations · 0 references
Natural SciencesPhysicsAstrophysicsComputational ChemistryQuantum ChemistryAb Initio MethodsComputational AstrophysicsAtomic Structure CalculationsAtomic Transition ProbabilitiesForbidden TransitionsMagnetic Dipole OperatorsTransition Probabilities
Making use of the atomic structure computer program SUPERSTRUCTURE, radiative transition probabilities are calculated for the forbidden lines in the ground configuration |$1s^2 2s^2 2p^6 3s^2 3p^3$| of all the members of the P I isoelectronic sequence up to Ni XIV. Elaborate procedures such as configuration interaction, relativistic corrections to the magnetic dipole operator, special radial wave functions and semi-empirical term energy corrections are used in the present calculation. This leads to considerable improvements over previous work. The importance of these changes is discussed in connection with some astrophysical problems.