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Intramolecular Photoredox Reaction of Naphthoquinone Derivatives
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2017
Year
Quinone ReductionEngineeringPhotoredox ProcessBiochemistryPhotochemistryNaphthoquinone DerivativesNatural SciencesMechanistic PhotochemistrySynthetic PhotochemistryPhotocatalysisOrganic ChemistryQuinone NucleusRedox ChemistryChemistryRedox Biology
Photoinduced intramolecular redox reaction of naphthoquinone derivatives is described, enabling C–H bond oxygenation at the α-position of the quinone nucleus and the quinone reduction under photoirradiation. The substrate scope and mechanistic insight are reported.