Sustained Water Oxidation by a Catalyst Cage‐Isolated in a Metal–Organic Framework

Abstract

Der Starke ist am mächtigsten allein: In den Poren eines MOF (hellblau im Bild) können Moleküle eines hoch reaktiven MnIII(μ-O)2MnIV-Wasseroxidationskatalysators (mehrfarbige Kugeln) isoliert werden. Das resultierende System katalysiert die Wasseroxidation bei minimierten intermolekularen Neben- und Zerfallsreaktionen. Auf diese Weise kann die Lebensdauer reaktiver Katalysatoren verlängert werden, ohne ihre molekulare Struktur verändern zu müssen. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.