Broadening the Action Spectrum of TiO2-Based Photocatalysts to Visible Region by Substituting Platinum with Copper

Abstract

In this study, TiO₂-based photocatalysts modified with Pt and Cu/CuO_x were synthesized and studied in the photocatalytic reduction of CO₂. The morphology and chemical states of synthesized photocatalysts were studied using UV-Vis diffuse reflectance spectroscopy, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy. A series of light-emitting diodes (LEDs) with maximum intensity in the range of 365-450 nm was used to determine the action spectrum of photocatalysts. It is shown for, the first time, that the pre-calcination of TiO₂ at 700 °C and the use of Cu/CuO_x instead of Pt allow one to design a highly efficient photocatalyst for CO₂ transformation shifting the working range to the visible light (425 nm). Cu/CuO_x/TiO₂ (calcined at 700 °C) shows a rate of CH₄ formation of 1.2 ± 0.1 µmol h^-1 g^-1 and an overall CO₂ reduction rate of 11 ± 1 µmol h^-1 g^-1 (at 425 nm).