Concepedia

‘In-water’, nickel-catalyzed mild preparation of allylic amines employing alcohols: application to ‘all-water’ synthesis of pharmaceuticals

Gargi Nikhil Vaidya, Ramesh Hiralal Choudhary, Mithilesh Nagpure, Shyam Kumar Lokhande, Pooja Rana, Dinesh Kumar

Green Chemistry · 2022 · 27 citations · 81 references

DOI

Concepts

Abstract

Reported here is a nanomicelle-enabled, ‘in-water’, nickel-catalyzed allylic amination reaction using allylic alcohols under mild conditions (in the absence of additives/bases/activators).

References

81

What is a green solvent? A comprehensive framework for the environmental assessment of solvents

Christian Capello, Ulrich Fischer, Konrad Hungerbühler · Green Chemistry · 2007 · 1.9K citations

, , +13

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

Bo Su, Zhi‐Chao Cao, Zhang‐Jie Shi · Accounts of Chemical Research · 2015 · 744 citations

, , +17

Scalable and sustainable electrochemical allylic C–H oxidation

Evan J. Horn, Brandon R. Rosen, Yong Chen et al. · Nature · 2016 · 738 citations · Full text

, , +10

TPGS-750-M: A Second-Generation Amphiphile for Metal-Catalyzed Cross-Couplings in Water at Room Temperature

Bruce H. Lipshutz, Subir Ghorai, Alexander R. Abela et al. · The Journal of Organic Chemistry · 2011 · 492 citations

, , +14

Green chemistry

Martyn Poliakoff, Pete Licence · Nature · 2007 · 399 citations

, , +10