Aziridinium cation templating 3D lead halide hybrid perovskites

Abstract

This study describes the synthesis of the first aziridinium-based compounds, namely hybrid perovskites (AzrH)PbHal₃ (where AzrH = aziridinium, Hal = Cl, Br or I). This highly reactive species was stabilized in 3D lead halide frameworks and was found to be a small enough organic cation to promote the formation of semiconducting organo-inorganic materials.