Concepedia

The hangman effect boosts hydrogen production by a manganese terpyridine complex

Qianqian Wu, Minghong Li, Shuanglin He, Ying Xiong, Ping Zhang, Heyan Huang, Lin Chen, Fang Huang, Fei Li

Chemical Communications · 2022 · 14 citations · 29 references

DOI

Concepts

Abstract

By virtue of a hangman effect, a manganese terpyridine complex catalyzes electrochemical hydrogen evolution from phenol in acetonitrile solution and achieves a turnover frequency of 525 s −1 with an overpotential of ca. 230 mV.

References

29

Proton-Coupled Electron Transfer Guidelines, Fair and Square

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[Mn(bipyridyl)(CO)<sub>3</sub>Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO<sub>2</sub> Reduction

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H<sub>2</sub> Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation

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The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H<sub>2</sub> Production Electrocatalysts:  Iron Hydrogenase Model Complexes

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[Ni(P<sup>Ph</sup><sub>2</sub>N<sup>C6H4X</sup><sub>2</sub>)<sub>2</sub>]<sup>2+</sup> Complexes as Electrocatalysts for H<sub>2</sub> Production: Effect of Substituents, Acids, and Water on Catalytic Rates

U.J. Kilgore, John A. S. Roberts, Douglas H. Pool et al. · Journal of the American Chemical Society · 2011 · 382 citations

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