Concepedia

Anion-induced disproportionation of Th(<scp>iii</scp>) complexes to form Th(<scp>ii</scp>) and Th(<scp>iv</scp>) products

Justin C. Wedal, Nathalia Cajiao, Michael L. Neidig, William J. Evans

Chemical Communications · 2022 · 10 citations · 20 references

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Concepts

Abstract

First example of disproportionation observed for a thorium complex.

References

20

Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C<sub>5</sub>H<sub>4</sub>SiMe<sub>3</sub>)<sub>3</sub>U]

Matthew R. MacDonald, Megan E. Fieser, Jefferson E. Bates et al. · Journal of the American Chemical Society · 2013 · 270 citations

, , +13

Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C<sub>5</sub>H<sub>3</sub>(SiMe<sub>3</sub>)<sub>2</sub>]<sub>3</sub>Th}<sup>1−</sup> anion containing thorium in the formal +2 oxidation state

Ryan R. Langeslay, Megan E. Fieser, Joseph W. Ziller et al. · Chemical Science · 2014 · 143 citations · Full text

, , +16

Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy

Alasdair Formanuik, Ana-Maria Ariciu, Fabrizio Ortu et al. · Nature Chemistry · 2016 · 136 citations · Full text

, , +14

Importance of Energy Level Matching for Bonding in Th<sup>3+</sup>-Am<sup>3+</sup> Actinide Metallocene Amidinates, (C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>[<sup>i</sup>PrNC(Me)N<sup>i</sup>Pr]An

Justin R. Walensky, Richard L. Martin, Joseph W. Ziller et al. · Inorganic Chemistry · 2010 · 120 citations

, , +17

Synthesis and Characterization of the First Sandwich Complex of Trivalent Thorium:  A Structural Comparison with the Uranium Analogue

Julian S. Parry, Cloke, Simon J. Coles et al. · Journal of the American Chemical Society · 1999 · 117 citations · Full text

, , +16