Biobased Composites with High Lignin Content and Excellent Mechanical Properties toward the Ingenious Photoresponsive Actuator

Abstract

The fabrication of biobased smart materials from renewable biomasses is of great importance for sustainable development. Although lignin possesses photothermal conversion potential, the development of lignin-based actuators with large contraction and fast photoresponse has various hurdles. Herein, simply by blending with castor oil-derived polyamide elastomers, a lignin-based photoresponsive actuator can be obtained, which accomplishes up to 18% light-driven contraction under loading within 3 s. The crystals in polymer matrix serve as switch segments, firmly locking the stress-induced strain energy, which is swiftly released due to photothermal processes and induced a huge contraction. The composite, LP₄-50, can contract and induce dynamic bending in multiple directions when irradiated locally with a near-infrared 808 nm laser. Furthermore, at standard 1 sun irradiation (100 mW/cm²), LP₄-50 was successfully employed to power a thermoelectric generator. This strategy establishes the groundwork for further research into the photothermal characteristics of lignin and encourages new applications in stimulus-responsive actuators.