Optimal robust stimulated Raman exact passage by inverse optimization

Abstract

We apply the inverse geometric optimization technique to generate an optimal and robust stimulated Raman exact passage (STIREP) considering the loss of the upper state as a characterization parameter. Control field temporal shapes that are optimal with respect to pulse area, energy, and duration are found to form a simple sequence with a combination of intuitively (near the beginning and the end) and counterintuitively ordered pulse pairs. The resulting dynamics produces a loss which is about a third of that of the nonrobust optimal STIREP. Alternative optimal solutions featuring lower losses, larger pulse areas, and fully counterintuitive pulse sequences are derived.