Publication | Closed Access
HP(O)Ph<sub>2</sub>/H<sub>2</sub>O-promoted hydrodefluorination of trifluoromethyl alkenes
31
Citations
42
References
2022
Year
Phosphoryl AnionTrifluoromethyl AlkenesEngineeringAlkene MetathesisFluorous SynthesisOrganic ChemistryChemistryGem -DifluoroalkenesHalogenationBiomolecular Engineering
An efficient transition-metal-free hydrodefluorination reaction of trifluoromethyl alkenes for accessing gem -difluoroalkenes is developed. It was surprising to find that the phosphoryl anion is able to mediate the defluorination.
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