Carbon Dioxide Chemically Responsive Switchable Gas Valves with Protonation‐Induced Liquid Gating Self‐Adaptive Systems

Abstract

Carbon dioxide (CO₂ ) capture and storage technologies are promising to limit CO₂ emission from anthropogenic activities, to achieve carbon neutrality goals. CO₂ capture requires one to separate CO₂ from other gases, and therefore a gas flow system that exhibits discernible gating behaviors for CO₂ would be very useful. Here we propose a self-adaptive CO₂ gas valve composed of chemically responsive liquid gating systems. The transmembrane critical pressures of the liquid gate vary upon the presence of CO₂ , due to the superamphiphiles assembled by poly(propylene glycol) bis(2-aminopropyl ether) and oleic acid in gating liquids that are protonated specifically by CO₂ . It is shown that the valve can perform self-adaptive regulation for specific gases and different concentrations of CO₂ . This protonation-induced liquid gating mechanism opens a potential platform for applications of CO₂ separators, detectors, sensors and beyond.