Concepedia

Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes

Jaime Ponce‐de‐León, Guillermo Marcos-Ayuso, Juan Á. Casares, Pablo Espinet

Chemical Communications · 2022 · 12 citations · 26 references

DOIFull text

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Concepts

Abstract

generation of the Cu nucleophile by rate determining C-H activation of highly fluorinated aryls (≥4 F atoms) leads to high cross-coupling selectivity with little formation of homocoupling products.

References

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