Fabrication of Bi2MoO6 Nanosheets/TiO2 Nanorod Arrays Heterostructures for Enhanced Photocatalytic Performance under Visible-Light Irradiation

Abstract

Bi₂MoO₆/TiO₂ heterostructures (HSs) were synthesized in the present study by growing Bi₂MoO₆ nanosheets on vertically aligned TiO₂ nanorod arrays using a two-step solvothermal method. Their morphology and structure were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. Excellent visible-light absorption was observed by UV-Vis absorption spectroscopy, which was attributed to the presence of the Bi₂MoO₆ nanosheets with a narrow-band-gap. The specific surface area and pore volume of the photocatalysts were significantly increased due to the hierarchical structure composed of Bi₂MoO₆ nanosheets and TiO₂ nanorods. The photoluminescence and photoelectrochemical characterizations showed improved separation and collection efficiency of the Bi₂MoO₆/TiO₂ HSs towards the interface charge carrier. The photocatalytic analysis of the Bi₂MoO₆/TiO₂ HSs demonstrated a significantly better methylene blue (MB) degradation efficiency of 95% within 3 h than pristine TiO₂ nanorod arrays under visible-light irradiation. After three photocatalytic cycles, the degradation rate remained at ~90%. The improved performance of the Bi₂MoO₆/TiO₂ HSs was attributed to the synergy among the extended absorption of visible light; the large, specific surface area of the hierarchical structure; and the enhanced separation efficiency of the photogenerated electron-hole pairs. Finally, we also established the Bi₂MoO₆/TiO₂ HSs band structure and described the photocatalytic dye degradation mechanism. The related electrochemical analysis and free-radical trapping experiments indicated that h⁺, ·O₂^- and ·OH have significant effects on the degradation process.