Hydrogenation of a Rhodium Peroxido Complex by Formate Derivatives: Mechanistic Studies and the Catalytic Formation of H₂O₂ from O₂

Abstract

Hydrierung von Disauerstoff: Der Rhodiumperoxidokomplex 1, erzeugt aus 2 und Disauerstoff, kann mit Diwasserstoffquellen unter Bildung von Wasserstoffperoxid reduziert werden. In einem Katalyseexperiment bei Normaldruck und Raumtemperatur wurde Wasserstoffperoxid in Gegenwart von 1 aus Disauerstoff und Ammoniumformiat erhalten (siehe Schema). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.