Integrated near-infrared QEPAS sensor based on a 28 kHz quartz tuning fork for online monitoring of CO2 in the greenhouse

Abstract

In this paper, a highly sensitive and integrated near-infrared CO₂ sensor was developed based on quartz-enhanced photoacoustic spectroscopy (QEPAS). Unlike traditional QEPAS, a novel pilot line manufactured quartz tuning fork (QTF) with a resonance frequency <i>f</i> ₀ of 28 kHz was employed as an acoustic wave transducer. A near-infrared DFB laser diode emitting at 2004 nm was employed as the excitation light source for CO₂ detection. An integrated near-infrared QEPAS module was designed and manufactured. The QTF, acoustic micro resonator (AmR), gas cell, and laser fiber are integrated, resulting in a super compact acoustic detection module (ADM). Compared to a traditional 32 kHz QTF, the QEPAS signal amplitude increased by > 2 times by the integrated QEPAS module based on a 28 kHz QTF. At atmospheric pressure, a 5.4 ppm detection limit at a CO₂ absorption line of 4991.25 cm^-1 was achieved with an integration time of 1 s. The long-term performance and stability of the CO₂ sensor system were investigated using Allan variance analysis. Finally, the minimum detection limit (MDL) was improved to 0.7 ppm when the integration time was 125 s. A portable CO₂ sensor system based on QEPAS was developed for 24 h continuous monitoring of CO₂ in the greenhouse located in Guangzhou city. The CO₂ concentration variations were clearly observed during day and night. Photosynthesis and respiration plants can be further researched by the portable CO₂ sensor system.