The Uranyl Cation as a Visible‐Light Photocatalyst for C(sp³)−H Fluorination

Abstract

Abstract The fluorination of unactivated C(sp 3 )−H bonds remains a desirable and challenging transformation for pharmaceutical, agricultural, and materials scientists. Previous methods for this transformation have used bench‐stable fluorine atom sources; however, many still rely on the use of UV‐active photocatalysts for the requisite high‐energy hydrogen atom abstraction event. Uranyl nitrate hexahydrate is described as a convenient, hydrogen atom abstraction catalyst that can mediate fluorinations of certain alkanes upon activation with visible light.