One-Center and Two-Center Self-Trapped Excitons in Zero-Dimensional Hybrid Copper Halides: Tricolor Luminescence with High Quantum Yields

Abstract

The organic-inorganic hybrid copper halides exhibit intriguing and complex photophysical properties, and the underlying mechanisms are far from clear. Here, we study the photodynamics of six novel types of low-dimensional hybrid copper halides, which have a maximum quantum yield of 98.6%. They exhibit two origins of photon emission with distinct temperature dependence and quantum transition rates. The experiments in junction with first-principles calculations indicate that they stem from two kinds of self-trapped excitons (STEs): one-center a-STE (localized on Cu⁺ monomer) and two-center m-STE (localized on Cu₂²⁺ dimer). There is phase transition between a-STE and m-STE when enough thermal energy is acquired for crossing the potential barrier between them. The degree of softness of the compositional organic cations of the copper halide plays a key role in determining the self-trapping type of the STEs.