Outstanding flame retardancy for poly(vinyl alcohol) achieved using a resveratrol/tannic acid complex

Abstract

Resveratrol/tannic acid-poly(vinyl alcohol) (RETA-PVA) blends have been prepared by compression molding using poly(vinyl alcohol), tannic acid and resveratrol as raw materials. The effects of different resveratrol/tannic acid ratios on the flammability of RETA-PVA blends have been studied. The flammability of the RETA-PVA blends was assessed using cone calorimetry, thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Results indicate that RETA-PVA molecules occur through hydrogen bonding and RETA-PVA blends are amorphous. The glass transition temperature for RETA-PVA-2 is the highest among all blends and the peak of heat release rate and smoke production rate for RETA-PVA is 38.4% and 43.9% lower than that for PVA, respectively. With the addition of resveratrol, the residual amount of RETA-PVA after complete combustion is greatly increased, to 30 times that for PVA, indicating that RETA-PVA blends display excellent flame retardant properties.