Concepedia

Thiazetidin-2-ylidenes as four membered N-heterocyclic carbenes: theoretical studies and the generation of complexes with N<sup>+</sup> center

Gurudutt Dubey, Nutan Mahawar, T.P. Singh, Nirjhar Saha, Subash C. Sahoo, Prasad V. Bharatam

Physical Chemistry Chemical Physics · 2021 · 16 citations · 37 references

DOI

Concepts

Abstract

Thiazetin-2-ylidene as a quantum chemically designed four-membered N-heterocyclic carbene possesses high singlet stability and nucleophilicity and forms NHC→N + ←(thiazetidin-2-ylidene) systems.

References

37

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N-Heterocyclic Carbenes: A Door Open to Supramolecular Organometallic Chemistry

Susana Ibáñez, Macarena Poyatos, Eduardo Peris · Accounts of Chemical Research · 2020 · 183 citations

, , +15