On the Role of Density‐Driven Dissolution of CO ₂ in Phreatic Karst Systems

Abstract

Abstract Density‐driven dissolution of carbon dioxide in water is a well‐known and much described mechanism in geological sequestration of this greenhouse gas. It is remarkable that such enhanced dissolution does not receive attention in karst hydrology and speleology. Models and hypotheses on karst development are complex and consider many different processes. We focus here on the influence of CO 2 partial gas pressures at the interface between atmosphere and karst water on the dynamics of dissolved CO 2 concentrations below the water table. Seasonal variations of microbial soil activity and root respiration or barometric‐pressure changes cause fluctuations in CO 2 partial pressures. Dependent on the existence and strength of a karst‐water background flow, fingering regimes might be triggered causing enhanced dissolution of CO 2 . This allows replenishment of CO 2 , and, thus, dissolutional power even deep in the water body without the need for percolating water to transport dissolved CO 2 . We present and discuss simplified and generic experimental and computational scenarios to strengthen our claim, and we try to give answers to: how much? and under which circumstances? The applied numerical model solves the Navier‐Stokes equation with water density dependent on CO 2 concentration and temperature. We show that calculated CO 2 mass fluxes into the water bodies are dependent on the ratio of Péclet to Rayleigh numbers (Pe/Ra) and show a local minimum around Pe/Ra = 1, i.e. when natural and forced convection are about equal. Concluding, we claim that there is sufficient reason to consider density‐driven dissolution as a process of relevance in karstification if circumstances are given.