Sn₇Br₁₀S₂: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

Abstract

Infrared nonlinear optical (IR NLO) materials are significant in laser technology for civil and military uses. Here, we report the synthesis, structural chemistry and NLO properties of a halogen-rich chalcohalide Sn₇ Br₁₀ S₂ . Its noncentrosymmetric (NCS, P6₃ ) structure can be considered as partially aliovalent anion substitution of SnBr₂ (P6₃ /m) induced centrosymmetric (CS) to NCS structural transformation. The 3D _∞ [Sn(1)₆ Sn(2)₆ Br₆ X₆ ]^6- (X=Br/S) channel framework consists of Sn(1)BrX₂ and Sn(2)X₃ trigonal pyramids. It exhibits excellent NLO performance, including a strong phase-matchable NLO response of 1.5 × AgGaS₂ and high laser-induced damage threshold of 6.3 × AgGaS₂ .Investigation of the structure-NLO performance relationship confirms that the effective arrangement of Sn(1)BrX₂ and Sn(2)X₃ units predominantly contributes to the large SHG response. These results indicate Sn₇ Br₁₀ S₂ is a potential IR NLO candidate and provides a new feasible system for promising NLO materials.