Bi5O7I/g-C3N4 Heterostructures With Enhanced Visible-Light Photocatalytic Performance for Degradation of Tetracycline Hydrochloride

Abstract

Bi₅O₇I/g-C₃N₄ p-n junctioned photocatalysts were synthesized by alcohol-heating and calcination in air. The structures, morphologies and optical properties of as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (DRS). Photocatalytic activity of the heterojunctioned composites were evaluated by degradation of Rhodamine B (RhB) and tetracycline hydrochloride (TCH) under visible light illumination. The results indicated that the composites exhibited superior efficiencies for photodegradation of RhB and TCH in comparison with pure BiOI, Bi₅O₇I and g-C₃N₄. An effective built-in electric field was formed by the interface between p-type Bi₅O₇I and n-type g-C₃N₄, which promoted the efficient separation of photoinduced electron-hole pairs. In addition, 8% Bi₅O₇I/g-C₃N₄ composite showed excellent photostability in a five-cycle photocatalytic experiment. Experiments on scavenging active intermediates revealed the roles of active species.