Bis[μ-bis(diphenylphosphino)methane-κ²<i>P</i>:<i>P</i>′]bis[diacetonitrilecopper(I)] bis(hexafluorophosphate)

Abstract

The title compound, [Cu2(μ2-dppm)2(MeCN)4](PF6)2 or [Cu2(C25H22P2)2(C2H3N)4](PF6)2, crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.