Historical Development of Research Methods in the Information Systems Discipline

René Riedl‬, David Rueckel

Americas Conference on Information Systems · 2011 · 17 citations · 39 references

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Abstract

Air-stable zinc(II) pyridyl phosphine complexes, [Zn(κ<sup>2</sup>-2,6-{Ph<sub>2</sub>PNMe}<sub>2</sub>(NC<sub>5</sub>H<sub>3</sub>))Br<sub>2</sub>] (1) and [Zn(κ<sup>2</sup>-2-{Ph<sub>2</sub>PNMe}(NC<sub>5</sub>H<sub>3</sub>))Br<sub>2</sub>] (2) are reported and 1 was capable of electrocatalytic reduction of CO<sub>2</sub> at -2.3 V <i>vs.</i> Fc<sup>+/0</sup> to yield CO/HCO<sub>2</sub>H in mixed water/acetonitrile solutions. DFT computations support a proposed mechanism involving electron transfer reactions from a species with the anionic PN<sup>3</sup>P ligand ("L<sup>-</sup>/Zn(II)").

References

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