Bimetallic Au@Pt Nanocrystal Sensitization Mesoporous α-Fe₂O₃ Hollow Nanocubes for Highly Sensitive and Rapid Detection of Fish Freshness at Low Temperature

Abstract

In this work, we present a new metal oxide semiconductor gas sensor for detecting trimethylamine (TMA) by bimetal Au@Pt-modified α-Fe₂O₃ hollow nanocubes (NCs) as sensing materials. The structure and morphological characteristics of Au@Pt/α-Fe₂O₃ were evaluated through multiple analyses, and their gas-sensitive performance was investigated. Compared with the pristine α-Fe₂O₃ NC sensor, the sensor based on Au@Pt/α-Fe₂O₃ NCs exhibited faster response time (5 s) and higher response (<i>R</i>_a/<i>R</i>_g = 32) toward 100 ppm TMA gas at a lower temperature (150 °C). Furthermore, we also assessed the Au@Pt/α-Fe₂O₃ NC sensor for detecting the freshness of <i>Larimichthys crocea</i> which have been observed by headspace solid-phase microextraction and gas chromatography-mass spectrometry. The high performance of the Au@Pt/α-Fe₂O₃ NCs is attributed to the special hollow morphology with a high specific surface area (212.9 m²/g) and the synergistic effect of the Au@Pt bimetal. The Au@Pt/α-Fe₂O₃ sensor shows promising application prospects in estimating seafood freshness on the spot.