Betti base derived <i>P</i>-stereogenic phosphine-diamidophosphite ligands with a single atom spacer and their application in asymmetric catalysis

Soumyadeep Chakrabortty, Katharina Konieczny, Bernd Müller, Anke Spannenberg, Paul C. J. Kamer, Johannes G. de Vries

Catalysis Science & Technology · 2021 · 17 citations · 26 references

Concepts

Abstract

Small bite-angle P -chirogenic PNP ligands have been synthesized stereo-selectively and employed in Rh-catalyzed asymmetric hydrogenation and Pd-catalyzed asymmetric allylic substitution resulting in moderate to excellent enantioselectivities.

References

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