Metal-free visible-light-promoted C(sp³)–H functionalization of aliphatic cyclic ethers using trace O₂

Abstract

Presented is a light-promoted C-C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst. This transformation proceeds in neat conditions through an auto-oxidation mechanism which is maintained through the leaching of trace amounts of O₂ as sole green oxidant.