Hierarchical coral-like MnCo ₂ O _4.5 @Co–Ni LDH composites on Ni foam as promising electrodes for high-performance supercapacitor

Abstract

Transition metal oxides are generally designed as hybrid nanostructures with high performance for supercapacitors by enjoying the advantages of various electroactive materials. In this paper, a convenient and efficient route had been proposed to prepare hierarchical coral-like MnCo₂O_4.5@Co-Ni LDH composites on Ni foam, in which MnCo₂O_4.5nanowires were enlaced with ultrathin Co-Ni layered double hydroxides nanosheets to achieve high capacity electrodes for supercapacitors. Due to the synergistic effect of shell Co-Ni LDH and core MnCo₂O_4.5, the outstanding electrochemical performance in three-electrode configuration was triggered (high area capacitance of 5.08 F cm^-2at 3 mA cm^-2and excellent rate capability of maintaining 61.69% at 20 mA cm^-2), which is superior to those of MnCo₂O_4.5, Co-Ni LDH and other metal oxides based composites reported. Meanwhile, the as-prepared hierarchical MnCo₂O_4.5@Co-Ni LDH electrode delivered improved electrical conductivity than that of pristine MnCo₂O_4.5. Furthermore, the as-constructed asymmetric supercapacitor using MnCo₂O_4.5@Co-Ni LDH as positive and activated carbon as negative electrode presented a rather high energy density of 220<i>μ</i>Wh cm^-2at 2400<i>μ</i>W cm^-2and extraordinary cycling durability with the 100.0% capacitance retention over 8000 cycles at 20 mA cm^-2, demonstrating the best electrochemical performance compared to other asymmetric supercapacitors using metal oxides based composites as positive electrode material. It can be expected that the obtained MnCo₂O_4.5@Co-Ni LDH could be used as the high performance and cost-effective electrode in supercapacitors.