Tetrathiafulvalene–Cobalt Metal–Organic Frameworks for Lithium-Ion Batteries with Superb Rate Capability

Abstract

Although pristine metal-organic framework (MOF) anodes for lithium-ion batteries (LIBs) show moderate activities and relatively stable cycling, the poor rate capability of the MOF anodes limited their applications in the development of a new generation of energy storage. Herein, the electric active Co^II ion is selected to coordinate with redox-active S-rich tetrathiafulvalene (TTF) derivatives to create two TTF-Co-MOFs, formulated as [Co₂(py-TTF-py)₂(BDC)₂]·2DMF·H₂O (TTF-Co-MOF <b>1</b>) and [Co₂(py-TTF-py)₂(BPDC)₂]·3DMF·3H₂O (TTF-Co-MOF <b>2</b>), where py-TTF-py = 2,6-bis(4'-pyridyl)tetrathiafulvalene, H₂BDC = terephthalic acid, H₂BPDC = biphenyl-4,4'-dicarboxylic acid, and DMF = <i>N</i>,<i>N</i>-dimethylformamide. Crystallographic characterization indicated that the two MOFs possess similar 2-fold-interpenetrating 3D frameworks but with two different pore sizes. The pore-size-dependent performances of the TTF-Co-MOFs were explored to optimize the MOFs as the anode materials for LIBs. TTF-Co-MOF <b>1</b> presents a high reversible specific capacity of 1186.6 mAh g^-1 at 200 mA g^-1 after 287 cycles. The rate capability is greatly enhanced by the introduction of Co^II into TTF-based MOFs with specific capacities of 1028.6 mAh g^-1 at 5 A g^-1 and 966.5 mAh g^-1 at 10 A g^-1. On the basis of the series analysis of theoretical calculations, electrochemical impedance spectroscopy, and crystal structures, it is found that the Co^II metal centers play a bridging role in charge transport within the MOF framework, which is beneficial for the transportation of Li ions. The competitive performances of TTF-Co-MOF <b>1</b> are attributed to the synergistic effect of the Co^II metal centers and S-rich TTF ligand as well as suitable porosity. The study shed some light for the fabrication of advanced energy storage devices through the rational design of MOF-based anode materials.