Advanced Functional Materials · 2021 · 274 citations · 37 references
Optical MaterialsEngineeringNegative-index MetamaterialAcoustic MetamaterialImpedance MatchRgo SpongeMetamaterialsElectromagnetic MetamaterialsGraphene-based Nano-antennasOptical PropertiesComputational ElectromagneticsRgo Sponge MetamaterialsElectromagnetic AbsorptionNanophotonicsHigh Impedance SurfacesMaterials SciencePhysicsAntennaOptical AntennasApplied PhysicsGrapheneDynamic MetamaterialsReduced Graphene Oxide
Reduced graphene oxide sponges show strong electromagnetic absorption at high frequencies, yet low‑frequency (2–4 GHz) absorption is difficult to achieve due to impedance‑matching and dielectric‑loss trade‑offs. The study reports rGO‑based metamaterials with various unit shapes to overcome this challenge. Experiments and simulations were employed to examine how the unit shape affects absorption performance. A frustum‑pyramid unit delivers ultrabroadband absorption (reflection loss < −10 dB from 2.4 to 40 GHz, average −22.9 dB over 2–40 GHz, 99 % absorption over a 32 GHz band) that is largely angle‑independent, owing to excellent impedance matching and strong dielectric loss, making the lightweight structure promising for broadband EM protection.
Abstract The reduced graphene oxide (rGO) sponges exhibit exciting electromagnetic absorption (MA) performance in high‐frequency range. However, it is still a great challenge to realize desirable MA property at low frequency (2–4 GHz) due to the great difficulty in balancing the good interfacial impedance matching and strong dielectric loss. Herein, the MA metamaterials based on rGO sponge with different unit shapes are reported. The relationship between the unit shape and MA performance is explored by experiment and simulation. The results show that frustum pyramid metamaterial exhibits ultrabroad band MA; the qualified absorption (the reflection loss lower than −10 dB) of electromagnetic wave can be achieved at 2.4–40 GHz. The average absorption intensity is −22.9 dB in the band of 2–40 GHz. Moreover, the bandwidth for strong absorption with an absorption rate of 99% (−20 dB) is up to 32 GHz. It is significant that the reflection loss has ignorant change even though the incident angle is increased from 5° to 40°. These are contributed to the excellent impedance matching and strong dielectric loss. These lightweight frustum pyramid metamaterials are very promising in the application for broadband electromagnetic protection.
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