Solar Urea: Towards a Sustainable Fertilizer Industry

Abstract

Urea, an agricultural fertilizer, nourishes humanity. The century-old Bosch-Meiser process provides the world's urea. It is multi-step, consumes enormous amounts of non-renewable energy, and has a large CO₂ footprint. Thus, developing an eco-friendly synthesis for urea is a priority. Herein we report a single-step Pd/LTA-3A catalyzed synthesis of urea from CO₂ and NH₃ under ambient conditions powered solely by solar energy. Pd nanoparticles serve the dual function of catalyzing the dissociation of NH₃ and providing the photothermal driving force for urea formation, while the absorption capacity of LTA-3A removes by-product H₂ O to shift the equilibrium towards urea production. The solar urea conversion rate from NH₃ and CO₂ is 87 μmol g^-1 h^-1 . This advance represents a first step towards the use of solar energy in urea production. It provides insights into green fertilizer production, and inspires the vision of sustainable, modular plants for distributed production of urea on farms.