Simultaneous Visual Detection and Removal of Cu²⁺ with Electrospun Self-Supporting Flexible Amidated Polyacrylonitrile/Branched Polyethyleneimine Nanofiber Membranes

Abstract

Sensitive detection and effective removal of copper ions (Cu²⁺) from water are still arduous tasks required to protect public health and environmental safety because of the serious impacts of Cu²⁺ on humans and other organisms. Herein, we report the design and fabrication of self-supporting flexible amidated polyacrylonitrile/branched polyethyleneimine nanofiber membranes (abbreviated as aPAN/BPEI NMs) <i>via</i> facile electrospinning and a subsequent hydrothermal method, which are used not only as strips for the visual detection of Cu²⁺ but also as effective adsorbents for the removal of Cu²⁺ from water. Because aPAN/BPEI NMs are self-supporting, they can be easily removed from the solution to reduce secondary pollution to the environment. Based on the high Cu²⁺ binding capacity of BPEI, Cu²⁺ ions are adsorbed on the aPAN/BPEI NMs, which leads to the appearance of new absorbance bands at 280 and 636 nm and a color change from yellow to blue. aPAN/BPEI NMs are utilized for the visual detection of Cu²⁺ with a linear range of 50-700 μM and limits of detection of 11.5 and 4.8 μM (absorption peaks at 280 and 636 nm). More importantly, aPAN/BPEI NMs exhibit excellent selectivity and certain recovery with a simple treatment. Furthermore, by utilizing the adsorption characteristics of Cu²⁺ in aqueous media, it can be effectively removed by aPAN/BPEI NMs with a remarkable adsorption capacity of 209.53 mg·g^-1. Additionally, the removal of Cu²⁺ by aPAN/BPEI NMs does not exhibit interference by other foreign ions. The adsorption process conforms well to the pseudo-second order (PSO) kinetic model and Jovanovich model, proving that adsorption occurs <i>via</i> chemical and monolayer adsorption mechanisms. Accordingly, this work will provide theoretical and technical support for the design and fabrication of novel heavy metal ion detection-removal integrated materials exhibiting high sensitivity and strong adsorption.