Solution combustion synthesis of Ni/La₂O₃ for dry reforming of methane: tuning the basicity <i>via</i> alkali and alkaline earth metal oxide promoters

Abstract

The production of syngas <i>via</i> dry reforming of methane (DRM) has drawn tremendous research interest, ascribed to its remarkable economic and environmental impacts. Herein, we report the synthesis of K, Na, Cs, Li, and Mg-promoted Ni/La₂O₃ using solution combustion synthesis (SCS). The properties of the catalysts were determined by N₂ physisorption experiments, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectrometry (XPS), and H₂-TPR (temperature programmed reduction). In addition, their catalytic performance towards DRM was evaluated at 700 °C. The results demonstrated that all catalysts exhibited porous structures with high specific surface area, in particular, Mg-promoted Ni/La₂O₃ (Mg-Ni-La₂O₃) which depicted the highest surface area and highest pore volume (54.2 m² g^-1, 0.36 cm³ g^-1). Furthermore, Mg-Ni-La₂O₃ exhibited outstanding catalytic performance in terms of activity and chemical stability compared to its counterparts. For instance, at a gas hourly space velocity (GHSV) of 30 000 mL g^-1 h^-1, it afforded 83.2% methane conversion and 90.8% CO₂ conversion at 700 °C with no detectable carbon deposition over an operating period of 100 h. The superb DRM catalytic performance of Mg-Ni-La₂O₃ was attributed to the high specific surface area/porosity, strong metal-support interaction (MSI), and enhanced basicity, in particular the strong basic sites compared to other promoted catalysts. These factors remarkably enhance the catalytic performance and foster resistance to coke deposition.