Concepedia

Metal-free hydrogen evolution cross-coupling enabled by synergistic photoredox and polarity reversal catalysis

Jilei Cao, Xiaona Yang, Lishuang Ma, Kanghui Lu, Rong Zhou

Green Chemistry · 2021 · 31 citations · 65 references

DOI

Concepts

Abstract

A visible-light photocatalytic hydrogen evolution cross-coupling of silanes with H 2 O, alcohols, phenols, and silanols via synergistic combination of photoredox and polarity reversal catalysis has been developed.

References

65

The Cross‐Dehydrogenative Coupling of CH Bonds: A Versatile Strategy for CC Bond Formations

Simon A. Girard, Thomas Knauber, Chao‐Jun Li · Angewandte Chemie International Edition · 2013 · 1.8K citations

, , +8

Silicon in organic, organometallic, and polymer chemistry

Choice Reviews Online · 2001 · 1.6K citations

, , +17

Organosilicon Molecules with Medicinal Applications

Annaliese K. Franz, Sean O. Wilson · Journal of Medicinal Chemistry · 2012 · 1.1K citations · Full text

, , +17

Donor–Acceptor Fluorophores for Visible-Light-Promoted Organic Synthesis: Photoredox/Ni Dual Catalytic C(sp<sup>3</sup>)–C(sp<sup>2</sup>) Cross-Coupling

Jian Luo, Jian Zhang · ACS Catalysis · 2016 · 843 citations

, , +16

Palladium-Catalyzed Cross-Coupling Reactions of Organosilanols and Their Salts: Practical Alternatives to Boron- and Tin-Based Methods

Scott E. Denmark, Christopher S. Regens · Accounts of Chemical Research · 2008 · 561 citations · Full text

, , +9