The construction of an artificial light-harvesting system with two-step sequential energy transfer based on supramolecular polymers

Abstract

An artificial light-harvesting system with two-step sequential energy transfer was constructed in aqueous media based on cyano-substituted <i>p</i>-phenylenevinylene derivative (PPTA) and bis-(<i>p</i>-sulfonatocalix[4]arenes) (BSC4) supramolecular polymers formed through host-guest interactions, in which two different fluorescent dyes, eosin Y (EY) and sulforhodamine (SR101), were employed as energy acceptors. The obtained artificial light-harvesting system can achieve an efficient two-step energy transfer process from PPTA-BSC4 to EY and then to SR101 with high energy-transfer efficiencies of up to 36.6% and 40.8%, respectively. More importantly, the harvested energy from the PPTA-BSC4 + EY + SR101 system can be used to promote the dehalogenation of α-bromoacetophenone with a yield of 89% in aqueous solution.