Concepedia

Ni-Catalyzed direct iminoalkynylation of unactivated olefins with terminal alkynes: facile access to alkyne-labelled pyrrolines

Xingjie Zhang, Di Qi, Chenchen Jiao, Zhiguo Zhang, Xiaopan Liu, Guisheng Zhang

Organic Chemistry Frontiers · 2021 · 22 citations · 71 references

DOI

Concepts

Abstract

The first example of iminoalkynylation of unactivated olefins with terminal alkynes was achieved by a nickel-catalyzed iminyl-radical cyclization/Sonogashira-type coupling sequence.

References

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Hartmuth C. Kolb, M. G. Finn, K. Barry Sharpless · Angewandte Chemie International Edition · 2001 · 9.3K citations · Full text

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[2+2+2] Cycloaddition Reactions Catalyzed by Transition Metal Complexes

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Alkyne-Tag Raman Imaging for Visualization of Mobile Small Molecules in Live Cells

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Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions

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