Concepedia

Cobalt-catalyzed coupling reactions of 2-halobenzamides with alkynes: investigation of ligand-controlled dual pathways

Vijaykumar H. Thorat, Hasil Aman, Yu‐Lin Tsai, Gangaram Pallikonda, Gary Jing Chuang, Jen‐Chieh Hsieh

Organic Chemistry Frontiers · 2021 · 17 citations · 65 references

DOI

Concepts

Abstract

The Co-catalyzed reactions of 2-halobenzamides and alkynes to form quinolinones or 2-vinyl benzamides are described here. These two reactions can be controlled merely by ligands.

References

65

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

Todd K. Hyster, Tomislav Rovis · Journal of the American Chemical Society · 2010 · 617 citations · Full text

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Cobalt‐Catalyzed, Aminoquinoline‐Directed C(sp<sup>2</sup>)H Bond Alkenylation by Alkynes

Liene Grigorjeva, Olafs Daugulis · Angewandte Chemie International Edition · 2014 · 503 citations · Full text

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Ruthenium‐Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds

Lutz Ackermann, Alexander V. Lygin, Nora Hofmann · Angewandte Chemie International Edition · 2011 · 465 citations · Full text

, , +15

Ruthenium‐Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds

Lutz Ackermann, Alexander V. Lygin, Nora Hofmann · Angewandte Chemie · 2011 · 431 citations

, , +15

Nickel-Catalyzed Chelation-Assisted Transformations Involving Ortho C–H Bond Activation: Regioselective Oxidative Cycloaddition of Aromatic Amides to Alkynes

Hirotaka Shiota, Yusuke Ano, Yoshinori Aihara et al. · Journal of the American Chemical Society · 2011 · 383 citations

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