Liquid‐Metal‐Enabled Mechanical‐Energy‐Induced CO₂ Conversion

Abstract

A green carbon capture and conversion technology offering scalability and economic viability for mitigating CO₂ emissions is reported. The technology uses suspensions of gallium liquid metal to reduce CO₂ into carbonaceous solid products and O₂ at near room temperature. The nonpolar nature of the liquid gallium interface allows the solid products to instantaneously exfoliate, hence keeping active sites accessible. The solid co-contributor of silver-gallium rods ensures a cyclic sustainable process. The overall process relies on mechanical energy as the input, which drives nano-dimensional triboelectrochemical reactions. When a gallium/silver fluoride mix at 7:1 mass ratio is employed to create the reaction material, 92% efficiency is obtained at a remarkably low input energy of 230 kWh (excluding the energy used for dissolving CO₂ ) for the capture and conversion of a tonne of CO₂ . This green technology presents an economical solution for CO₂ emissions.