Electronic Materials · 2021 · 32 citations · 66 references
Natural SciencesMaterials EngineeringMaterials ScienceMaterials ChemistryNanomaterialsOptical MaterialsCarbon NanotubesElectro-optic EffectsElectro-optic MaterialsLiquid CrystalsNanocompositesNanotubesBirefringenceLiquid Crystal Dielectric PropertiesLiquid Crystal Electro-optic EffectLiquid Crystal NanocompositesMulti-walled Carbon NanotubesNematic Liquid CrystalsUltrafast Optical ResponseViscosity
In this paper, we investigate a commercial nematic liquid crystal (LC) mixture namely E7 dispersed with small concentrations of multi-walled carbon nanotubes (MWCNTs). The dielectric and electro-optical characterizations have been carried out in the homogeneously and vertically aligned LC cells. The electro-optical response of LC molecules has been enhanced by 60% after the addition of MWCNTs, which is attributed to the reduced rotational viscosity in the composites. MWCNTs act like barricades for ionic impurities by reducing them up to ∼34.3% within the dispersion limit of 0.05 wt%. The nematic–isotropic phase transition temperature (TNI) of the E7 LC has also been shifted towards the higher temperature, resulting in a more ordered nematic phase. The enhanced birefringence and orientational order parameter in the LC-MWCNTs are attributed to π-π electron stacking between the LC molecules and the MWCNTs. The outlined merits of the LC-MWCNTs composites evince their suitability for ultrafast nematic-based electro-optical devices.
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