Heterostructural Interface in Fe₃C-TiN Quantum Dots Boosts Oxygen Reduction Reaction for Al–Air Batteries

Abstract

Oxygen reduction electrocatalysts play important roles in metal-air batteries. Herein, Fe₃C-TiN heterostructural quantum dots loaded on carbon nanotubes (FCTN@CNTs) are prepared as electrocatalysts for the oxygen reduction reaction (ORR) through a one-pot pyrolysis. The Fe₃C-TiN quantum dots with a diameter of 2-5 nm show the unique characteristic of heterostructural interface. The as-prepared FCTN@CNTs display Pt/C comparable ORR performance (<i>E</i>_onset 1.06 and <i>E</i>_1/2 0.95 V) in alkaline medium, which is ascribed to the heterostructural interface between TiN and Fe₃C. Furthermore, the Al-air batteries with the FCTN@CNT catalyst display superior discharge performance, demonstrating good feasibility for practical application. This work provides an effective new method to synthesize affordable and efficient oxygen reduction reaction catalysts.